Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/212312
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dc.contributor.authorMoreno‐Cabrerizo, Cristinaes_ES
dc.contributor.authorOrtega‐Martínez, Aitores_ES
dc.contributor.authorEsteruelas, Miguel A.es_ES
dc.contributor.authorLópez, Ana M.es_ES
dc.contributor.authorNájera, Carmenes_ES
dc.contributor.authorSansano, José M.es_ES
dc.date.accessioned2020-05-27T09:33:53Z-
dc.date.available2020-05-27T09:33:53Z-
dc.date.issued2020-05-29-
dc.identifier.citationEuropean Journal of Organic Chemistry 2020(20): 3101-3109 (2020)es_ES
dc.identifier.issn1434-193X-
dc.identifier.urihttp://hdl.handle.net/10261/212312-
dc.description.abstractThe synthesis of 3,3'‐bioxindoles employing deacylative alkylations (DaA) in one‐pot process, where the 3‐bromooxindoles are generated in situ, is described. Good yields and moderate diastereoselections are obtained. By the modification of this procedure the synthesis of pure 3‐bromooxindoles through a deacylative bromination (DaB) is achieved. These bromides are efficiently employed in a photoredox dimerization process to get the desired 3,3'‐bioxindoles in good yields and low diastereoselections. In this single‐electron‐transfer (SET) mechanism the presence of a high quantum‐yield iridium(III) complex ensures high conversions in short reaction times.es_ES
dc.description.sponsorshipWe gratefully acknowledge financial support from the Spanish Ministerio de Ciencia, Innovación y Universidades (projects CTQ2016‐81893REDT, and RED2018‐102387‐T) the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016‐76782‐P, CTQ2016‐80375‐P and CTQ2017‐82935‐P), the Generalitat Valenciana (PROMETEOII/2014/017), the University of Alicante, and Gobierno de Aragón (Group E06_17R and project LMP148_18). A. O.‐M. thanks MINECO for a predoctoral fellowship.es_ES
dc.language.isoenges_ES
dc.publisherJohn Wiley & Sonses_ES
dc.relationCTQ2017-82935-P/AEI/10.13039/501100011033es_ES
dc.relationMICIU/ICTI2017-2020/CTQ2017-82935-P-
dc.relationMINECO/ICTI2013-2016/CTQ2016‐81893-REDT-
dc.relationMICIU/ICTI2017-2020/RED2018‐102387‐T-
dc.relationRED2018‐102387‐T/AEI/10.13039/501100011033-
dc.relationMINECO/ICTI2013-2016/CTQ2016‐76782-P-
dc.relationMINECO/ICTI2013-2016/CTQ2016‐80375‐P-
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.subjectPhotoredox catalysises_ES
dc.subjectBioxindoleses_ES
dc.subjectIridiumes_ES
dc.subjectDacylative brominationes_ES
dc.subjectDeacylative alkylationes_ES
dc.titleDeacylative alkylation vs. photoredox catalysis in the synthesis of 3,3'‐bioxindoleses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1002/ejoc.202000375-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1002/ejoc.202000375es_ES
dc.identifier.e-issn1099-0690-
dc.embargo.terms2021-05-29es_ES
dc.contributor.funderMinisterio de Ciencia, Innovación y Universidades (España)es_ES
dc.contributor.funderMinisterio de Economía, Industria y Competitividad (España)es_ES
dc.contributor.funderAgencia Estatal de Investigación (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderGeneralitat Valencianaes_ES
dc.contributor.funderUniversidad de Alicantees_ES
dc.contributor.funderGobierno de Aragónes_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.relation.csices_ES
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dc.identifier.funderhttp://dx.doi.org/10.13039/501100010067es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010198es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100011033es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003359es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/100009092es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
item.grantfulltextopen-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
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