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dc.contributor.authorMiranda, Pedro O.es_ES
dc.contributor.authorRamírez, Miguel A.es_ES
dc.contributor.authorPadrón, Juan I.es_ES
dc.contributor.authorMartín, Víctor S.es_ES
dc.date.accessioned2020-05-26T17:18:13Z-
dc.date.available2020-05-26T17:18:13Z-
dc.date.issued2006-01-16-
dc.identifier.citationTetrahedron Letters 47(3): 283-286 (2006)es_ES
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10261/212260-
dc.description.abstractA study on a novel oxonia [3,3]-sigmatropic rearrangement as competitive alternative pathway to the acetylenic Prins cyclization on the addition of secondary homopropargylic alcohols to aldehydes catalyzed by iron(III) is described. ‘Ab initio’ theoretical calculations of the species involved on the rearrangement supports the in situ formation of 2,3-allenolates. The domino process involves three consecutive chemical events in one-pot format reaction (∼70% average).es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relation.isversionofPostprintes_ES
dc.rightsclosedAccesses_ES
dc.subject[3,3]-Sigmatropic rearrangementes_ES
dc.subjectPrins cyclizationes_ES
dc.subjectIron(III) halideses_ES
dc.titleIn situ generation of 2,3-allenolates in the coupling of secondary homopropargylic alcohols and aldehydeses_ES
dc.typeartículoes_ES
dc.identifier.doihttp://dx.doi.org/10.1016/j.tetlet.2005.11.032-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.tetlet.2005.11.032es_ES
dc.rights.licensehttps://creativecommons.org/licenses/by/4.0/es_ES
dc.contributor.funderMinisterio de Ciencia y Tecnología (España)es_ES
dc.contributor.funderGobierno de Canariases_ES
dc.relation.csicNoes_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100006280es_ES
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