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dc.contributor.authorMiranda, Pedro O.es_ES
dc.contributor.authorCarballo, Rubén M.es_ES
dc.contributor.authorRamírez, Miguel A.es_ES
dc.contributor.authorMartín, Víctor S.es_ES
dc.contributor.authorPadrón, Juan I.es_ES
dc.date.accessioned2020-05-26T16:05:39Z-
dc.date.available2020-05-26T16:05:39Z-
dc.date.issued2006-11-29-
dc.identifier.citationArkivoc: Online Journal Organic Chemistry (4): 331-343 (2007)es_ES
dc.identifier.issn1551-7012-
dc.identifier.urihttp://hdl.handle.net/10261/212248-
dc.description.abstractAn unexpected halide exchange with halogenated solvents using iron(III) halides as promoters in oxa- and aza-alkyne Prins cyclizations have been observed. The process is specific for alkynes, while during the Prins cyclization using both homoallylic alcohols and N-tosyl amines, the halide participation from the halogenated solvent was absent. Calculation at ab initio level provides substantiation of the proposed model.es_ES
dc.language.isoenges_ES
dc.publisherUniversity of Michigan-
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccesses_ES
dc.subjectPrins cyclizationes_ES
dc.subjectAza-Prins cyclizationes_ES
dc.subjectFe(III) halideses_ES
dc.subjectVinyl cationses_ES
dc.subjectHalogen abstractiones_ES
dc.titleUnexpected halogen exchange with halogenated solvents in the iron(III) promoted oxa-alkyne and aza-alkyne Prins cyclizationses_ES
dc.typeartículoes_ES
dc.identifier.doi10.3998/ark.5550190.0008.430-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.3998/ark.5550190.0008.430es_ES
dc.identifier.e-issn1551-7004-
dc.rights.licensehttps://creativecommons.org/licenses/by/4.0/es_ES
dc.contributor.funderMinisterio de Educación y Ciencia (España)es_ES
dc.contributor.funderGobierno de Canariases_ES
dc.relation.csicNoes_ES
oprm.item.hasRevisionno ko 0 false*
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