English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/211804
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Ferric chloride: A mild and versatile reagent for the formation of 1,6-anhydro glucopyranoses

AuthorsMiranda, Pedro O. ; Brouard, Ignacio ; Padrón, Juan I. ; Bermejo, Jaime
KeywordsFerric chloride
1,6-anhydro glucopyranoses
Lewis acid
Issue Date12-May-2003
PublisherElsevier BV
CitationTetrahedron Letters 44(20): 3931-3934 (2003)
AbstractA novel method for the preparation of 1,6-anhydro glucopyranoses (mono- and disaccharides) utilizing anhydrous FeCl3 as Lewis acid is described. Treatment of methyl 6-O-benzyl and 6-O-p-methoxybenzyl-α/β D-glucopyranosides derivatives with FeCl3 in CH2Cl2 at room temperature and 40°C afforded 1,6-anhydro glucopyranosides in moderate to good yields, through a debenzylation and intramolecular glycosidation in one step. A plausible reaction pathway is proposed.
Publisher version (URL)https://doi.org/10.1016/S0040-4039(03)00821-9
URIhttp://hdl.handle.net/10261/211804
Identifiersdoi: 10.1016/S0040-4039(03)00821-9
issn: 0040-4039
Appears in Collections:(IPNA) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.