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Title

Chiral Microenvironments in Self-Assembled Capsules

AuthorsNuckolls, Colin; Hof, Fraser; Martín, Tomás ; Rebek, Julius Jr.
KeywordsMolecules
Encapsulation
Noncovalent interactions
Molecular structure
Cavities
Issue Date21-Oct-1999
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 121(44): 10281-10285 (1999)
AbstractA nonracemic compound is synthesized and shown to assemble reversibly through hydrogen bonding to form a cyclic tetramer. The chiral arrangement of atoms in the individual pieces becomes amplified through self-assembly to yield multiple functional groups asymmetrically arranged within the cavity. The tetrameric capsule shows a special affinity for ketones and is able to discriminate between their enantiomers in solution.
Publisher version (URL)https://doi.org/10.1021/ja992779m
URIhttp://hdl.handle.net/10261/211790
DOI10.1021/ja992779m
ISSN0002-7863
E-ISSN1520-5126
Appears in Collections:(IPNA) Artículos
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