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| Title: | Chiral Microenvironments in Self-Assembled Capsules |
| Authors: | Nuckolls, Colin; Hof, Fraser; Martín, Tomás  ; Rebek, Julius Jr. |
| Keywords: | Molecules Encapsulation Noncovalent interactions Molecular structure Cavities |
| Issue Date: | 21-Oct-1999 |
| Publisher: | American Chemical Society |
| Citation: | Journal of the American Chemical Society 121(44): 10281-10285 (1999) |
| Abstract: | A nonracemic compound is synthesized and shown to assemble reversibly through hydrogen bonding to form a cyclic tetramer. The chiral arrangement of atoms in the individual pieces becomes amplified through self-assembly to yield multiple functional groups asymmetrically arranged within the cavity. The tetrameric capsule shows a special affinity for ketones and is able to discriminate between their enantiomers in solution. |
| Publisher version (URL): | https://doi.org/10.1021/ja992779m |
| URI: | http://hdl.handle.net/10261/211790 |
| DOI: | 10.1021/ja992779m |
| ISSN: | 0002-7863 |
| E-ISSN: | 1520-5126 |
| Appears in Collections: | (IPNA) Artículos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| accesoRestringido.pdf | Artículo principal | 16,34 kB | Adobe PDF |  View/Open |
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