English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/211755
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Double Cationic Propargylation: From Linear to Polycyclic Ethers

AuthorsDíaz, David ; Martín, Tomás ; Martín, Víctor S.
KeywordsDiols
Ethers
Cyclization
Substitution reactions
Issue Date15-Sep-2001
PublisherAmerican Chemical Society
CitationOrganic Letters 3(21): 3289-3291 (2001)
AbstractThe trapping of cations generated from Co2(CO)6-bispropargylic alcohols provided diethers in good yield. The procedure is also valid when two vicinal acetylenes are present. The methodology can be applied to the synthesis of symmetrical or unsymmetrical linear or cyclic propargylic ethers. The use of substrates with a stereochemically defined secondary nucleophilic alcohol provided cyclic ethers with a high degree of stereocontrol.
Publisher version (URL)https://doi.org/10.1021/ol0164987
URIhttp://hdl.handle.net/10261/211755
DOI10.1021/ol0164987
ISSN1523-7060
E-ISSN1523-7052
Appears in Collections:(IPNA) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdfArtículo principal16,34 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.