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Title

Stereoselective synthesis of syn-2,7-disubstituted-4,5-oxepenes

AuthorsDíaz, David D.; Betancort, Juan M.; Pinacho Crisóstomo, Fernando R. ; Martín, Tomás ; Martín, Víctor S.
KeywordsMarine metabolites
Oxepenes
Nicholas reaction
Issue Date4-Mar-2002
PublisherElsevier
CitationTetrahedron 58(10): 1913-1919 (2002)
AbstractAn efficient synthesis of the title compounds as pure enantiomers is reported. The method is based on the intramolecular trapping of a carbocation generated by acid treatment of exo-Co2(CO)6-propargyl alcohols by a stereochemically controlled secondary hydroxy group located in a suitable chain.
Publisher version (URL)https://doi.org/10.1016/S0040-4020(02)00046-7
URIhttp://hdl.handle.net/10261/211754
DOI10.1016/S0040-4020(02)00046-7
ISSN0040-4020
Appears in Collections:(IPNA) Artículos
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