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Title

Stereoselective Synthesis of Cyclic Ethers by Intramolecular Trapping of Dicobalt Hexacarbonyl-Stabilized Propargylic Cations

AuthorsBetancort, Juan M.; Martín, Tomás ; Palazón, José M.; Martín, Víctor S.
KeywordsAlcohols
Cyclization
Diols
Ethers
Toxins
Issue Date18-Mar-2003
PublisherAmerican Chemical Society
CitationJournal of Organic Chemistry 68(8): 3216–3224
AbstractThe intramolecular attack of a hydroxy group on an exo-biscobalthexacarbonyl propargylic cation provides cyclic ethers with six- to nine-membered rings. The scope and limitations of the methodology are described. The reaction is stereoselective when additional stereocenters are present, providing iterative methodology to access ladder-like cyclic ethers.
Publisher version (URL)https://doi.org/10.1021/jo0340556
URIhttp://hdl.handle.net/10261/211747
DOI10.1021/jo0340556
ISSN0022-3263
E-ISSN1520-6904
Appears in Collections:(IPNA) Artículos
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