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Title

The cis-2-alkyl-3-oxy-tetrahydropyran unit as a building block for new ionophores with C2-symmetry

AuthorsCarrillo Fumero, Romen ; Martı́n, Victor S.; Martín, Tomás
KeywordsIonophores
Lariat ethers
Template effect
Issue Date28-Jun-2004
PublisherElsevier
CitationTetrahedron Letters 45 (27): 5215-5219 (2004)
AbstractThe use of cis-2-alkyl-3-oxy-tetrahydropyran unit is reported as a novel structure for the design and synthesis of a new type of ionophore with C2-symmetry. The synthesis of five macrolides and their complexation properties were investigated. The template effect as an effective tool to improve the selectivity and yield in the macrolactonization process is described. The cis-2-alkyl-3-oxy-tetrahydropyran unit as a novel structure for the design and synthesis of a new type of ionophore with C2-symmetry is reported. The synthesis of five macrolides and their complexation properties were investigated.
Publisher version (URL)https://doi.org/10.1016/j.tetlet.2004.05.036
URIhttp://hdl.handle.net/10261/211708
DOI10.1016/j.tetlet.2004.05.036
ISSN0040-4039
Appears in Collections:(IPNA) Artículos
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