English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/210812
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:


Co2P2O7-Ni2P2O7 solid solutions: Structural characterization and color

AuthorsTena, M. A.; Mendoza-Meroño, R.; Trobajo, Camino ; García, José R. ; García-Granda, Santiago
Issue Date2019
PublisherAmerican Ceramic Society
John Wiley & Sons
CitationJournal of the American Ceramic Society 102(6): 3695-3704 (2019)
AbstractNH4[Co1−yNiyPO4]·H2O (0 ≤ y ≤ 1) single crystals were fired to prepare Co2−xNixP2O7 0 ≤ x ≤ 2 solid solutions between 800 and 1200°C. The structure of these solid solutions is α‐M2P2O7 (M = Co, Ni). The contraction of the unit cell with increasing x confirmed the formation of these solid solutions. The UV–vis–NIR spectra of these solid solutions were consistent with Co(II) and Ni(II) ions in the two different crystallographic sites (octahedral site and square pyramidal site) in the α‐M2P2O7 structure. Due to their thermal stability, Co2−xNixP2O7 (0 ≤ x ≤ 2) solid solutions with α‐M2P2O7 structure can be used as a blue, green, brown or yellow ceramic pigment.
Publisher version (URL)https://doi.org/10.1111/jace.16158
Identifiersdoi: 10.1111/jace.16158
issn: 0002-7820
Appears in Collections:(CINN) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.