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Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule

AuthorsGarcía-Simón, Cristina; Monferrer, Alba; Garcia-Borràs, Marc; Imaz, Inhar ; Maspoch, Daniel ; Costas, Miquel; Ribas, Xavi
Issue Date2019
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 55(6): 798-801 (2019)
AbstractA novel naphthalene-based 5·(BArF) 8 capsule allows for the size-selective inclusion of C 60 from fullerene mixtures. Its size selectivity towards C 60 has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF) 8 encapsulates C 60 -derivatives such as C 60 -PCBM and N-methylpyrrolidine-C 60 . The latter can be separated from C 60 since 5·(BArF) 8 displays distinct affinity for them.
Publisher version (URL)https://doi.org/10.1039/c8cc07886f
Identifiersdoi: 10.1039/c8cc07886f
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(CIN2) Artículos
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