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Title

Metal-Catalyzed Hydrofunctionalization Reactions of Haloalkynes

AuthorsCadierno, Victorio
Issue Date2019
CitationEuropean Journal of Inorganic Chemistry (2019)
AbstractMetal-catalyzed hydrofunctionalization reactions of alkynes, i.e. the addition of E–H units (E = heteroatom or carbon) across the C≡C bond, are of key importance in modern synthetic chemistry. In recent years, haloalkynes have been successfully involved in these types of transformations, thus opening new atom-economical routes for the generation, among others, of haloalkenes, a pivotal class of compounds for cross-coupling processes. In particular, several catalytic systems able to promote the selective addition of C–H, O–H, N–H, S–H and X–H (X = halide) bonds to haloalkynes have been reported. This chemistry is comprehensively discussed in this Minireview article.
Publisher version (URL)http://dx.doi.org/10.1002/ejic.201901016
URIhttp://hdl.handle.net/10261/209842
Identifiersdoi: 10.1002/ejic.201901016
issn: 1099-0682
Appears in Collections:(IQAC) Artículos
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