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Optimising hydrogen production: Via solar acetic acid photoreforming on Cu/TiO 2

AuthorsImizcoz, Mikel; Puga, Alberto V.
Issue Date20-Feb-2019
PublisherRoyal Society of Chemistry (UK)
CitationCatalysis Science and Technology 9: 1098-1102 (2019)
AbstractValorisation of aqueous acetic acid - a model bio-oil component - by solar photocatalysis on Cu/TiO is efficient, yet decarboxylation tends to dominate over photoreforming due to copper co-catalyst oxidation. Selectivities to hydrogen were greatly enhanced by in situ photoreduction, ensuring the removal of passivation layers to unmask active Cu(0) surfaces, in a reversible fashion.
Publisher version (URL)http://dx.doi.org/10.1039/c8cy02349b
Identifiersdoi: 10.1039/c8cy02349b
issn: 2044-4761
Appears in Collections:(ITQ) Artículos
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