Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/209560
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Limousin, Elodie | - |
dc.contributor.author | Martínez-Tong, Daniel E. | - |
dc.contributor.author | Ballard, Nicholas | - |
dc.contributor.author | Asua, José M. | - |
dc.date.accessioned | 2020-04-29T08:20:24Z | - |
dc.date.available | 2020-04-29T08:20:24Z | - |
dc.date.issued | 2019-08-09 | - |
dc.identifier | doi: 10.1021/acsapm.9b00507 | - |
dc.identifier | issn: 2637-6105 | - |
dc.identifier.citation | ACS Applied Polymer Materials 1(8): 2213-2223 (2019) | - |
dc.identifier.uri | http://hdl.handle.net/10261/209560 | - |
dc.description.abstract | Acrylic/alkyd hybrid latexes offer the potential to obtain hard films from waterborne polymer dispersions without using coalescing agents. However, despite being widely used commercially, the curing process of the alkyd resin used in such formulations, and its influence on the final film morphology, remain poorly understood. In this work, we explore the curing process and its influence on film morphology in alkyd/acrylic hybrid latexes by nanomechanical mapping of the film during curing. It is shown that, although acrylic domains aid oxygen diffusion and facilitate curing, the rate of curing was substantially lower in the interior. Nevertheless, homogeneous curing was achieved at long times. The role of primary and secondary catalysts in the process is also explored, finding that the variation of the rate of curing of the alkyd plays an influential role in the development of film structure due to phase migration of the two polymers as curing progresses. It is hoped this work goes some way to unraveling the mystery behind the curing process in acrylic/alkyd hybrid latex films. | - |
dc.description.sponsorship | N.B. acknowledges the financial support obtained through the Post-Doctoral fellowship Juan de la Cierva− Incorporacion (No. IJCI-2016-28442), from the Ministry of ́ Economy and Competitiveness of Spain. D.E.M. acknowledges the financial support obtained through the Post-Doctoral fellowship Juan de la Cierva−Incorporacion (No. IJCI-2017- ́ 31600), from the Ministry of Economy and Competitiveness of Spain. | - |
dc.language | eng | - |
dc.publisher | ACS Publications | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-28442 | - |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/IJCI-2017-31600 | - |
dc.relation | IJCI-2017-31600/AEI/10.13039/501100011033 | - |
dc.rights | closedAccess | - |
dc.subject | Hybrid latex | - |
dc.subject | Film structure | - |
dc.subject | Curing | - |
dc.subject | Nanomechanical mapping | - |
dc.title | Cure-Dependent Morphology of Acrylic/Alkyd Hybrid Latex Films via Nanomechanical Mapping | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/acsapm.9b00507 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acsapm.9b00507 | - |
dc.date.updated | 2020-04-29T08:20:25Z | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (España) | - |
dc.contributor.funder | Agencia Estatal de Investigación (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011033 | es_ES |
dc.contributor.orcid | Limousin, Elodie [0000-0002-8789-8313] | - |
dc.contributor.orcid | Martínez-Tong, Daniel E. [0000-0002-3115-6222] | - |
dc.contributor.orcid | Ballard, Nicholas [0000-0002-9480-2922] | - |
dc.contributor.orcid | Asua, José M. [0000-0002-7771-1543] | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
Aparece en las colecciones: | (CFM) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
17
checked on 24-abr-2024
WEB OF SCIENCETM
Citations
15
checked on 28-feb-2024
Page view(s)
144
checked on 24-abr-2024
Download(s)
27
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.