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Title

Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: efficient construction of fused 5-7-5 tricyclic systems

AuthorsBhargava, Gaurav; Trillo, Beatriz; Araya, Marisel; López, Fernando; Castedo, Luis; Mascareñas, José L.
KeywordsPalladium-catalyzed [3C + 2C + 2C]
Alkylidenecyclopropanes
Cycloaddition
Alkynes
Alkenes
Issue Date10-Feb-2010
AbstractWe report a Pd-catalyzed intramolecular [3C + 2C + 2C] cycloaddition between alkylidenecyclopropanes, alkynes and alkenes. The method provides synthetically relevant 5-7-5 tricyclic structures, with good chemoselectivity and complete diastereoselectivity.
DescriptionChemical Communications 46(2): 270 - 272 (2010)
Publisher version (URL)http//dx.doi.org/ 10.1039/b919258a
http://www.rsc.org/ej/CC/2010/b919258a.pdf
URIhttp://hdl.handle.net/10261/20935
DOI10.1039/b919258a
Appears in Collections:(IQOG) Artículos
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