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dc.contributor.authorSonsona, Isaac G.-
dc.contributor.authorMarqués-López, Eugenia-
dc.contributor.authorGimeno, M. Concepción-
dc.contributor.authorHerrera, Raquel P.-
dc.date.accessioned2020-04-22T10:18:24Z-
dc.date.available2020-04-22T10:18:24Z-
dc.date.issued2019-07-16-
dc.identifierdoi: 10.1039/c9nj02392e-
dc.identifiere-issn: 1369-9261-
dc.identifierissn: 1144-0546-
dc.identifier.citationNew Journal of Chemistry 43(31): 12233-12240 (2019)-
dc.identifier.urihttp://hdl.handle.net/10261/208612-
dc.description.abstractThis work provides an unprecedented example of a chiral aromatic amine used to activate α,β-unsaturated ketones in asymmetric aminocatalysis. Chiral aromatic diamine VII has been efficiently employed, as a proof of concept, in the Michael addition reaction between benzylideneacetones (1a-f) and coumarins (2a-d). The reaction gives rise to warfarin derivatives 3 with promising results using this family of catalysts for the first time. The additional studies performed supported the bifunctional mode of activation of the chiral catalyst VII and the covalent nature of the interactions between the catalyst VII and benzylideneacetones 1.-
dc.description.sponsorshipThis work was supported by a 2018 Leonardo Grant for Researchers and Cultural Creators, BBVA Foundation. The authors also thank Ministerio de Economía, Industria y Competitividad (MINECO-FEDER CTQ2016-75816-C2-1-P and CTQ2017-88091-P), Universidad de Zaragoza (JIUZ-2017-CIE-05) and Gobierno de Aragón-Fondo Social Europeo (Research Group E07_17R) for financial support of their research. We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI).-
dc.languageeng-
dc.publisherRoyal Society of Chemistry (UK)-
dc.relationMINECO/ICTI2013-2016/CTQ2016-75816-C2-1-P-
dc.relationMICIU/ICTI2017-2020/CTQ2017-88091-P-
dc.relationCTQ2017-88091-P/AEI/10.13039/501100011033-
dc.relation.isversionofPublisher's version-
dc.rightsopenAccess-
dc.titleFirst aromatic amine organocatalysed activation of α,β-unsaturated ketones-
dc.typeartículo-
dc.identifier.doihttp://dx.doi.org/10.1039/c9nj02392e-
dc.relation.publisherversionhttp://doi.org/10.1039/c9nj02392e-
dc.date.updated2020-04-22T10:18:24Z-
dc.rights.licensehttp://creativecommons.org/licenses/by/4.0/-
dc.contributor.funderFundación BBVA-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderMinisterio de Ciencia, Innovación y Universidades (España)-
dc.contributor.funderAgencia Estatal de Investigación (España)-
dc.contributor.funderUniversidad de Zaragoza-
dc.contributor.funderGobierno de Aragón-
dc.contributor.funderEuropean Commission-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010067es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/100007406es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100011033es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100007041es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.contributor.orcidSonsona, Isaac G.[ 0000-0001-9988-0287]-
dc.contributor.orcidMarqués-López, Eugenia [0000-0001-6832-8983]-
dc.contributor.orcidGimeno, M. Concepción [0000-0003-0553-0695]-
dc.contributor.orcidHerrera, Raquel P. [0000-0002-5244-9569]-
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