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Título: | Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes |
Autor: | Guzmán, Jefferson CSIC; Torguet Forradellas, Adrián; García-Orduña, Pilar CSIC ORCID; Lahoz, Fernando J. CSIC ORCID; Oro, Luis A. CSIC ORCID; Fernández-Álvarez, Francisco J. CSIC ORCID | Palabras clave: | CO2-Reduction Rhodium Homogenous catalysis Silylcarbamates Hydrosilylation |
Fecha de publicación: | 1-oct-2019 | Editor: | Elsevier | Citación: | Journal of Organometallic Chemistry 897: 50-56 (2019) | Resumen: | The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSi–H, 1) with [RhCl(coe)] gives the rhodium(III) complex [Rh(Cl)(κ-NSi)] (2), which reacts with a stoichiometric amount of AgCFCO to afford [Rh(κ-CFCO)(κ-NSi)] (3). Complexes 2 and 3 have been fully characterized by elemental analysis and NMR spectroscopy. The solid-state structure of 3 has been confirmed by X-ray diffraction analysis. Moreover, the activity of complex 3 as catalyst for the reaction of secondary amines with CO (3 bar) and hydrosilanes has been studied. The outcomes of these catalytic studies show that under these conditions complex 3 promotes the selective formation of silylcarbamates. | Versión del editor: | http://doi.org/10.1016/j.jorganchem.2019.06.010 | URI: | http://hdl.handle.net/10261/208549 | DOI: | 10.1016/j.jorganchem.2019.06.010 | Identificadores: | doi: 10.1016/j.jorganchem.2019.06.010 issn: 0022-328X |
Aparece en las colecciones: | (ISQCH) Artículos |
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