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Designed asymmetric coordination helicates with bis-β-diketonate ligands

AuthorsDiego, Rosa; Darawsheh, Mohanad; Barrios, L. A.; Sadurní, Anna; Garcia, Jordi; Lloyd-Williams, Paul; Teat, Simon J.; Roubeau, Olivier; Aguilà, D.; Aromí, Guillem
Issue Date2019
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 48(45): 16844-16847 (2019)
AbstractA new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(III) and Ga(III) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups.
Publisher version (URL)https://doi.org/10.1039/C9DT03398J
Appears in Collections:(ICMA) Artículos
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