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Title

Sintering kinetics, defect chemistry and room-temperature mechanical properties of titanium nitride prepared by spark plasma sintering

AuthorsMorgado Chávez, J. M.; Moshtaghioun, Bibi Malmal; Cumbrera, F. L.; Gómez-García, D.
KeywordsTitanium nitride
SPS sintering
Titanium vacancies
Mechanical properties
Issue Date2019
PublisherElsevier
CitationJournal of Alloys and Compounds 807: 151666 (2019)
AbstractFully dense titanium nitride polycrystals have been prepared by spark plasma sintering. The kinetics of the sintering process and the optimized conditions for SPS processing have been put forward. Microstructural analyses of the resulting samples have unambiguously shown the coexistence of titanium as Ti, Ti and Ti, thus driving the presence of cation vacancies. This fact is a new ingredient which is shown to influence the mechanical properties of this strategic ceramic.
Publisher version (URL)https://doi.org/10.1016/j.jallcom.2019.151666
URIhttp://hdl.handle.net/10261/207976
Identifiersdoi: 10.1016/j.jallcom.2019.151666
issn: 0925-8388
e-issn: 1873-4669
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