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Título: | Thermochemistry of germanium and organogermanium compounds |
Autor: | Becerra, R. CSIC ORCID; Walsh, R. | Fecha de publicación: | 28-nov-2018 | Editor: | Royal Society of Chemistry (UK) | Citación: | Physical Chemistry Chemical Physics 21: 988-1008 (2019) | Resumen: | This article reviews the current state of thermochemistry (enthalpies of formation) of germanium and organogermanium compounds. While the emphasis is on data from experimental measurements, results of quantum chemical (ab initio) calculations are also included. We provide a set of current best values for GeX compounds (X = H, Me, F, Cl, Br, I) as well as mixed GeXY compounds. Also included are Ge/C/H, Ge/C/H/O and Ge/C/H/N compounds and Ge and Ge containing molecules. Further inclusions are data for species such as GeX (free radicals), GeX (germylenes) and π-bonded molecules which play prominent roles as intermediates in many thermal and photochemical reactions of germanium compounds. Bond dissociation enthalpies are derived for most commonly encountered Ge-X bonds. The evaluation of preferred values is assisted by exploiting relationships (increments, substituent effects) within specific series and between series. | Descripción: | 21 pags., 30 tabs. | Versión del editor: | http://dx.doi.org/10.1039/c8cp06208k | URI: | http://hdl.handle.net/10261/206839 | DOI: | 10.1039/c8cp06208k | Identificadores: | doi: 10.1039/c8cp06208k issn: 1463-9076 |
Aparece en las colecciones: | (IQF) Artículos |
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Thermochemistry of Germanium.doc | 702,5 kB | Microsoft Word | Visualizar/Abrir |
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