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Title

Advances in the phototriggered synthesis of single-chain polymer nanoparticles

AuthorsVerde-Sesto, Ester ; Blázquez-Martín, Agustín; Pomposo, José A.
KeywordsPhotochemistry
Photofolding
Single-chain nanoparticles
Issue Date18-Nov-2019
PublisherMultidisciplinary Digital Publishing Institute
CitationPolymers 11(11): 1903 (2019)
AbstractClean use of photons from light to activate chemical reactions offers many possibilities in different fields, from chemistry and biology to materials science and medicine. This review article describes the advances carried out in last decades toward the phototriggered synthesis of single-chain polymer nanoparticles (SCNPs) as soft nanomaterials with promising applications in enzyme-mimicking catalysis and nanomedicine, among other different uses. First, wesummarize some different strategies developed to synthesize SCNPs based on photoactivated intrachain homocoupling, phototriggered intrachain heterocoupling and photogenerated collapse induced by an external cross-linker. Next, we comprehensively review the emergent topic of photoactivated multifolding applied to SCNP construction. Finally, we conclude by summarizing recent strategies towards phototriggered disassembly of SCNPs.
Publisher version (URL)http://dx.doi.org/10.3390/polym11111903
URIhttp://hdl.handle.net/10261/203016
Identifiersdoi: 10.3390/polym11111903
issn: 2073-4360
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