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dc.contributor.authorMancebo-Aracil, Juanes_ES
dc.contributor.authorCasagualda, Carolinaes_ES
dc.contributor.authorMoreno-Villaécija, Miguel Ángeles_ES
dc.contributor.authorNador, Fabianaes_ES
dc.contributor.authorGarcía-Pardo, Javieres_ES
dc.contributor.authorFranconetti-García, Antonioes_ES
dc.contributor.authorBusqué, Félixes_ES
dc.contributor.authorAlibés, Ramónes_ES
dc.contributor.authorEsplandiú, María J.es_ES
dc.contributor.authorRuiz Molina, Danieles_ES
dc.contributor.authorSedó, Josepes_ES
dc.date.accessioned2020-02-10T13:00:23Z-
dc.date.available2020-02-10T13:00:23Z-
dc.date.issued2019-
dc.identifier.citationChemistry - A European Journal 25(53): 12367-12379 (2019)es_ES
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10261/200162-
dc.description.abstractThe combination of the surface‐adhesive properties of catechol rings and functional moieties conveying specific properties is very appealing to materials chemistry, but the preparation of catechol derivatives often requires elaborate synthetic routes to circumvent the intrinsic reactivity of the catechol ring. In this work, functional catechols are synthesized straightforwardly by using the bioinspired reaction of several functional thiols with o‐benzoquinone. With one exception, the conjugated addition of the thiol takes place regioselectively at the 3‐position of the quinone, and is rationalized by DFT calculations. Overall, this synthetic methodology provides a general and straightforward access to functional and chain‐extended catechol derivatives, which are later tested with regard to their hydro‐/oleophobicity, colloidal stability, fluorescence, and metal‐coordinating capabilities in proof‐of‐concept applications.es_ES
dc.description.sponsorshipC.C. and M.A.M.‐V. are grateful to the Spanish Ministry of Science for their predoctoral grants (FPU‐2015‐03245 and FPI‐SEV‐2013‐0295‐16‐1). F.N. is grateful to the Universidad Nacional del Sur for a postdoctoral grant. This project had financial support from the Spanish Ministry of Science and EU FEDER funds (CTQ2016‐75363‐R and MAT2015‐70615‐R).es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.relationMINECO/ICTI2013-2016/SEV‐2013‐0295es_ES
dc.relationMINECO/ICTI2013-2016/CTQ2016-75363-Res_ES
dc.relationMINECO/ICTI2013-2016/MAT2015-70615-Res_ES
dc.relation.isversionofPostprint-
dc.rightsopenAccessen_EN
dc.titleBioinspired functional catechol derivatives through simple thiol conjugate additiones_ES
dc.typeartículoes_ES
dc.identifier.doi10.1002/chem.201901914-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201901914es_ES
dc.identifier.e-issn1521-3765-
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderMinisterio de Ciencia e Innovación (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderUniversidad Nacional del Sures_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100005740es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004837es_ES
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