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http://hdl.handle.net/10261/200140
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Garzón-Tovar, Luis | es_ES |
dc.contributor.author | Pérez-Carvajal, Javier | es_ES |
dc.contributor.author | Yazdi, Amirali | es_ES |
dc.contributor.author | Hernández-Muñoz, Jose | es_ES |
dc.contributor.author | Tarazona, Pedro | es_ES |
dc.contributor.author | Imaz, Inhar | es_ES |
dc.contributor.author | Zamora, Félix | es_ES |
dc.contributor.author | Maspoch, Daniel | es_ES |
dc.date.accessioned | 2020-02-10T11:55:58Z | - |
dc.date.available | 2020-02-10T11:55:58Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | Angewandte Chemie International Edition 58(28): 9512-9516 (2019) | es_ES |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10261/200140 | - |
dc.description.abstract | Herein, we describe a new class of porous composites comprising metal–organic framework (MOF) crystals confined in single spherical matrices made of packed covalent‐organic framework (COF) nanocrystals. These MOF@COF composites are synthesized through a two‐step method of spray‐drying and subsequent amorphous (imine‐based polymer)‐to‐crystalline (imine‐based COF) transformation. This transformation around the MOF crystals generates micro‐ and mesopores at the MOF/COF interface that provide far superior porosity compared to that of the constituent MOF and COF components added together. We report that water sorption in these new pores occurs within the same pressure window as in the COF pores. Our new MOF@COF composites, with their additional pores at the MOF/COF interface, should have implications for the development of new composites. | es_ES |
dc.description.sponsorship | This work was supported by the Spanish MINECO (projects PN MAT2016‐77608‐C3‐1‐P, FIS2017‐86007‐C3 and FPU2015/0248), the Catalan AGAUR (project 2014 SGR 80), the ERC, under EU‐FP7 (ERC‐Co 615954), and the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV‐2017‐0706). IFIMAC is supported by the Maria de Maeztu program (Grant No. MDM‐2014‐0377). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley-VCH | es_ES |
dc.relation | FIS2017-86007-C3/AEI/10.13039/501100011033 | - |
dc.relation | SEV-2017-0706/AEI/10.13039/501100011033 | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-77608-C3-1-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/FIS2017-86007-C3 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/615954 | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/SEV-2017-0706 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MDM-2014-0377 | es_ES |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | es_ES |
dc.title | A MOF@COF composite with enhanced uptake through interfacial pore generation | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1002/anie.201904766 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/anie.201904766 | es_ES |
dc.identifier.e-issn | 1521-3773 | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación (España) | - |
dc.contributor.funder | Agencia Estatal de Investigación (España) | - |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (España) | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | Generalitat de Catalunya | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100002809 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011033 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
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