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Título: | Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems |
Autor: | Hidalgo, Nereida; Moreno, Juan José; Pérez-Jiménez, Marina; Maya, Celia CSIC ORCID; López-Serrano, Joaquín CSIC ORCID CVN; Campos, Jesús CSIC ORCID CVN | Palabras clave: | Frustrated Lewis Pair Heterobimetallic Inverse kinetic isotopic effect Hydrogen splitting Cooperative chemistry |
Fecha de publicación: | 12-may-2020 | Editor: | John Wiley & Sons | Citación: | Chemistry - A European Journal 26(27): 5982-5993 (2020) | Resumen: | A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) metal‐only frustrated Lewis pairs is described herein. We have also investigated the drastic effects on H 2 activation derived from subtle ligand modifications. The importance of the balance between bimetallic adduct formation and complete frustration has been interrogated, providing for the first time evidence for genuine metal‐only FLP reactivity in solution. The origin of a strong inverse kinetic isotopic effect has also been clarified, offering further support for the proposed bimetallic FLP‐type cleavage of dihydrogen. | Versión del editor: | https://doi.org/10.1002/chem.201905793 | URI: | http://hdl.handle.net/10261/199695 | DOI: | 10.1002/chem.201905793 | ISSN: | 0947-6539 | E-ISSN: | 1521-3765 |
Aparece en las colecciones: | (IIQ) Artículos |
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ChemEurJ_preprint_sin formato.pdf | 1,54 MB | Adobe PDF | Visualizar/Abrir |
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