English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/19906
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Dehydration of Ca3Al2(SiO4)y(OH)4(3−y) (0 < y < 0.176) studied by neutron thermodiffractometry

AutorRivas-Mercury, J. M.; Pena, Pilar; Aza Moya, Antonio H. de; Turrillas, Xavier
Palabras claveThermal treatment
Neutron powder diffraction
X-ray methods
Thermal expansion
Calcium aluminates
Fecha de publicación2008
CitaciónJournal of the European Ceramic Society 28(9): 1737-1748 (2008)
ResumenHydrogarnet (Ca12Al2(OH)12) and katoite of composition Ca3Al2(SiO4)0.176(OH)11.3 were obtained by hydration of tricalcium aluminium oxide, and for katoite synthesis, by addition of amorphous silica. The thermal dehydration was monitored in situ, by neutron thermodiffractometry, from room temperature to 700 °C at atmospheric pressure and at a heating rate of 2 °C/min. On heating, powder neutron diffraction patterns were collected every 300 s. Cell parameters were fitted by the Pawley method. Hydrogarnet decomposed to yield Ca12Al14O32(OH)·mH2O and Ca(OH)2 that eventually transformed to CaO. For katoite, phases of formula Ca12Al14−ySiyO32(O,OH)1+y/2 related to mayenite were formed. Complementary annealing experiments, for 10 h, at higher temperatures and subsequent quenching lead to the formation of mayenite and traces of Ca3SiO5. Thermogravimetric curves were in agreement with the thermodiffractometry experiments. Also, neutron diffraction data allowed to measure thermal expansion coefficients, at atmospheric pressure, between 25 and 250 °C for hydrogarnet and katoite: 1.89 × 10−5 ± 0.09 and 1.63 × 10−5 ± 0.07 °C−1, respectively.
Versión del editorhttp://dx.doi.org/10.1016/j.jeurceramsoc.2007.12.038
Aparece en las colecciones: (ICV) Artículos
(IETCC) Artículos
Ficheros en este ítem:
No hay ficheros asociados a este ítem.
Mostrar el registro completo

NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.