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dc.contributor.authorBarranco-García, Rosaes_ES
dc.contributor.authorGómez-Elvira González, José Manueles_ES
dc.contributor.authorRessia, Jorge A.es_ES
dc.contributor.authorQuinzani, Lidiaes_ES
dc.contributor.authorValles, Enrique M.es_ES
dc.contributor.authorPérez, Ernestoes_ES
dc.contributor.authorCerrada, María L.es_ES
dc.identifier.citationMicroporous and Mesoporous Materials 294 : 109945 (2020)es_ES
dc.description.abstractDifferent nanocomposites based on two isotactic polypropylenes (iPP) and mesoporous SBA-15 silica have been attained by melt extrusion as an attempt to understand the influence of average molecular weight in the rheological behavior, morphological and crystalline features and in the final properties (thermal stability and mechanical response) as well as in the capability of incorporating iPP chains within the nanometric SBA-15 pores. Closeness to rheological percolation and a significant increase of viscosity are observed as SBA-15 content is raised, this effect being more evident for the materials prepared from the iPP with the lowest molecular weight. These composites also shift their maximum degradation to lower values under inert atmosphere but keep rather unchanged decomposition behavior in oxidant conditions. No considerable changes are found with molecular weight in their morphological characteristics, nor in the type of iPP polymorph developed. The confinement of iPP chains in the SBA-15 channels, implied by a small endotherm in the DSC melting curves, is definitely ascertained by real-time variable-temperature Small Angle X-ray Scattering measurements with synchrotron radiation, suggesting, additionally, that somewhat thicker crystallites are developed within the mesostructure in the materials prepared from the iPP with inferior molecular weight. Moreover, the SBA-15 mesoporous particles exert a reinforcing role in all cases and reduce the deformation capacity of the ultimate materials as their content is increased.es_ES
dc.description.sponsorshipThis work was supported by the Agencia Estatal de Investigación (AEI, Spain) together with the European Regional Development Fund (FEDER, UE) (MAT2016-79869-C2-1-P project). Ms. R Barranco-García also thanks her pre-doctoral funding (BES-2014-070972) associated with the MINECO (MAT2013-47972-C2-1-P) project. The synchrotron experiments were performed at beamline BL11-NCD at ALBA Synchrotron Light Facility with the collaboration of ALBA staff. Authors are grateful for the funding received to perform these measurements.es_ES
dc.subjectiPP/SBA-15 nanocompositeses_ES
dc.subjectRheological percolationes_ES
dc.subjectSynchrotron SAXS measurementses_ES
dc.subjectMolecular weightes_ES
dc.titleEffect of iPP molecular weight on its confinement within mesoporous SBA-15 silica in extruded iPP-SBA-15 nanocompositeses_ES
dc.description.peerreviewedPeer reviewedes_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
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