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Unusual mesomorphic behaviour of an ethynyl-substituted phthalocyanine

AuthorsGarcía-Frutos, Eva M. ; Bottari, Giovanni ; Vázquez, Purificación; Barberá, Joaquín; Torres, Tomás
Issue Date2006
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications (29): 3107-3109 (2006)
AbstractAn ethynyl-substituted nickel(II) phthalocyanine has been synthesised and its thermotropic properties studied; optical microscopy, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques revealed an unusual mesomorphic behaviour observed for the first time in phthalocyanine systems where each disk of the hexagonal columnar mesophase is formed by two ethynyl-substituted phthalocyanine units.
Description3 pages, 1 figure, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1039/b604731a
Appears in Collections:(ICMA) Artículos
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