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Formation and characterization of a benzoquinolate triplatinum cluster containing a μ3-PPh2 bridging system and two Pt–Pt bonds

AuthorsDíez, Alvaro; Forniés, Juan CSIC; García, Ana; Lalinde, Elena; Moreno, M. Teresa
KeywordsCluster compounds
Bridging phosphido ligands
X-ray structure
Issue DateMar-2006
CitationInorganic Chemistry Communications 9(3): 255-258 (2006)
AbstractThe reaction between [Pt(bzq)(μ-PPh2)]2 and cis-[Pt(C6F5)2(thf)2] (1:2 molar ratio) results in the formation of a bent benzoquinolate triplatinum cluster [Pt3(bzq)(μ-PPh2)2(C6F5)3] 1, which has been characterized by X-ray crystallography. The structure shows the presence of μ2-PPh2 and [μ3-PPh(1,2-η2-Ph)-κ3P] bridging ligands and two platinum–platinum bonds.
Description4 pages, 1 figure, 1 appendix.
Publisher version (URL)http://dx.doi.org/10.1016/j.inoche.2005.11.012
Appears in Collections:(ICMA) Artículos
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