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Synthesis and catalytic activity of cationic allyl complexes of nickel stabilized by a single N-heterocyclic carbene ligand

AuthorsCámpora, Juan ; Ortiz de la Tabla, Laura; Palma, Pilar ; Álvarez, Eleuterio ; Lahoz, Fernando J. ; Mereiter, Kurt
Issue DateJun-2006
PublisherAmerican Chemical Society
CitationOrganometallics 25(14): 3314-3316 (2006)
AbstractCationic allylnickel complexes stabilized by a single N-heterocyclic carbene ligand (NHC) and a labile aquo or acetonitrile ligand have been synthesized by protonation of aryloxide-containing precursors. These complexes catalyze the polymerization of 1,3-butadiene and styrene, mimicking the analogous phosphine-based system.
Description3 pages, 2 figures, 1 scheme.-- Supporting Information Available: http://pubs.acs.org.
Publisher version (URL)http://dx.doi.org/10.1021/om060439l
Appears in Collections:(IIQ) Artículos
(ICMA) Artículos
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