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http://hdl.handle.net/10261/19685
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Mohr, Fabian | - |
dc.contributor.author | Falvello, Larry R. | - |
dc.contributor.author | Laguna, Mariano | - |
dc.date.accessioned | 2009-12-18T09:40:05Z | - |
dc.date.available | 2009-12-18T09:40:05Z | - |
dc.date.issued | 2005-12-20 | - |
dc.identifier.citation | European Journal of Inorganic Chemistry 2006(4): 833-838 (2005) | en_US |
dc.identifier.uri | http://hdl.handle.net/10261/19685 | - |
dc.description | 6 pages, 2 schemes, 1 figure. | en_US |
dc.description.abstract | A series of vinylgold(I) complexes [Au(CR=CHR)L] (R = H, Me; L = PPh3, PPh2Me, PPhMe2) were prepared from the reaction of the Grignard reagents [MgBr(CR=CHR)] (R = H, Me) with the gold(I) phosphane complexes [AuCl(L)] (L = PPh3, PPh2Me, PPhMe2) at low temperature. The complexes were characterised by various spectroscopic techniques and, in the case of [Au(CMe=CHMe)(PPh3)], by a single-crystal X-ray structure determination. The gold-carbon bonds of these vinylgold(I) complexes are easily cleaved by acids and, in the presence of potassium permanganate, by species containing acidic protons. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) | en_US |
dc.format.extent | 10752 bytes | - |
dc.format.mimetype | application/octet-stream | - |
dc.language.iso | eng | en_US |
dc.publisher | Wiley-VCH | en_US |
dc.rights | closedAccess | en_US |
dc.subject | Gold | en_US |
dc.subject | Vinyl ligands | en_US |
dc.subject | Phosphane ligands | en_US |
dc.title | Synthesis, structural characterisation and reactions of some vinylgold(I) phosphane complexes. | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1002/ejic.200500861 | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1002/ejic.200500861 | en_US |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.languageiso639-1 | en | - |
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