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Determination of the self-association and inter-association equilibrium constants of a carboxylic acid and its mixtures with pyridine derivates

AuthorsGonzález, Ana I.; Irusta, S.; Fernández-Berridi, M. J.; Iruin, J. J.; Sierra, Teresa; Oriol, Luis
Supramolecular chemistry
Inter-association equilibrium constants
Polycatenar benzoic acid
Issue Date30-May-2006
CitationVibrational Spectroscopy 41(1): 21-27 (2006)
AbstractInfrared spectroscopy has been employed to determine absorptivity coefficients and the self-association equilibrium constant of 3,4,5-tris(dodecyloxy)benzoic acid in cyclohexane. The obtained value is consistent with data reported in bibliography for other similar compounds. The equilibrium constant describing ethylpyridine/carbonyl hydrogen bonds has been determined for mixtures of the above-mentioned acid and two ethylpyridine isomers. The effect of steric hindrance is discussed.
Description7 pages, 7 figures, 3 tables.
Publisher version (URL)http://dx.doi.org/10.1016/j.vibspec.2005.12.003
Appears in Collections:(ICMA) Artículos
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