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Title

Synthesis of heteroleptic nickel(II) and palladium(II) dithiolenes

AuthorsLardiés, Nora; Cerrada, Elena ; Laguna, Mariano
KeywordsHeteroleptic dithiolenes
Nickel
Palladium
Issue DateOct-2006
PublisherElsevier
CitationPolyhedron 25(14): 2785-2790 (2006)
AbstractDeprotection of 4-(p-cyanophenyl)-1,3-dithiole-2-thione, 4-(2-thienyl)-1,3-dithiole-2-one (1) and 4-(3-thienyl)-1,3-dithiole-2-one (2) with a base in MeOH or KOH and the posterior addition of nickel(II) and palladium(II) complexes give the formation of heteroleptic dithiolenes with 1,2-bis(diphenylphosphino)ethane, dppe, as an additional ligand. The X-ray analyses of two Pd-dithiolenes show a planar five-membered ring involving the metallic center and the dithiolene unit.
Description6 pages, 3 tables, 2 figures, 1 scheme, 1 appendix.
Publisher version (URL)http://dx.doi.org/10.1016/j.poly.2006.04.010
URIhttp://hdl.handle.net/10261/19594
DOI10.1016/j.poly.2006.04.010
ISSN0277-5387
Appears in Collections:(ICMA) Artículos
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