English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/19592
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
DC FieldValueLanguage
dc.contributor.authorMerino, Pedro-
dc.contributor.authorJiménez, Pablo-
dc.contributor.authorTejero, Tomás-
dc.date.accessioned2009-12-15T14:11:29Z-
dc.date.available2009-12-15T14:11:29Z-
dc.date.issued2006-05-
dc.identifier.citationJournal of Organic Chemistry 71(12): 4685-4688 (2006)en_US
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/10261/19592-
dc.description4 pages, 2 schemes, 1 table.-- Supporting Information Available: http://pubs.acs.org.en_US
dc.description.abstractThe addition of a 2-silyloxy silylketene acetal to N-benzyl-2,3-O-isopropylidene-d-glyceraldehyde nitrone (Mannich-type reaction) can be stereocontrolled to give 2S,3S,4S and 2R,3R,4S adducts as major compounds, depending on whether the reaction is activated with zinc(II) triflate or tin(IV) chloride, respectively. The corresponding major adducts were used for preparing diastereomeric polyhydroxy-β-aminoesters that were further converted into suitable orthogonally protected enantiomeric d- and l-erythro-sphingosines.en_US
dc.description.sponsorshipThis study was supported by the Ministerio de Educacion y Ciencia (MEC), FEDER Program (Madrid, Spain, project CTQ2004-0421), and the Gobierno de Aragón (Zaragoza, Spain). P.J. thanks MEC for a FPU predoctoral grant.en_US
dc.format.extent259768 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsclosedAccessen_US
dc.titleEnantiodivergent synthesis of d- and l-erythro-sphingosines through mannich-type reactions of N-benzyl-2,3-O-isopropylidene-d-glyceraldehyde nitroneen_US
dc.typeartículoen_US
dc.identifier.doi10.1021/jo060465t-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1021/jo060465ten_US
Appears in Collections:(ICMA) Artículos
Files in This Item:
There are no files associated with this item.
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.