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Título

Synthesis and characterization of supramolecular polymeric materials containing azopyridine units

AutorMillaruelo, Marta; Chinellato, Luiz S.; Oriol, Luis; Piñol, Milagros; Serrano, José Luis; Tejedor, Rosa M.
Palabras claveAzo polymers
Liquid-crystalline polymers (LCP)
Supramolecular polymers
Fecha de publicaciónnov-2006
EditorWiley-Blackwell
CitaciónMacromolecular Chemistry and Physics 207(22): 2112-2120 (2006)
ResumenThe synthesis and characterization of a series of supramolecular polymeric complexes formed by H-bonding interactions between benzoic acid and azopyridine derivatives are described. A series of polymeric networks have been synthesized using a polymethacrylate bearing benzoic acid units as side groups, and several polymers with azopyridine as H-acceptor side groups. Furthermore, low-molecular-weight pyridine derivatives have been used to prepare an homologous side-chain polymer, and a network with azopyridine as a non-covalent crosslinker. Special attention was paid to the thermal and mesomorphic properties of these materials, which were studied by DSC, POM, and XRD.
Descripción9 pages, 8 figures, 3 tables.
Versión del editorhttp://dx.doi.org/10.1002/macp.200600345
URIhttp://hdl.handle.net/10261/19558
DOI10.1002/macp.200600345
ISSN1022-1352
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