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Título

Magnetothermal properties of molecule-based materials

AutorEvangelisti, Marco; Luis, Fernando; Jongh, L. J. de; Affronte, M.
Fecha de publicación14-mar-2006
EditorRoyal Society of Chemistry (Great Britain)
CitaciónJournal of Materials Chemistry 16(26): 2534-2549 (2006)
ResumenWe critically review recent results obtained by studying the low-temperature specific heat of some of the most popular molecule-based materials. After introducing the experimental techniques and basic theoretical framework needed for heat capacity determination and understanding, we report on the magnetothermal properties of molecular antiferromagnetic wheels. For selected molecular high-spin clusters, particular emphasis is devoted to magnetic quantum tunnelling and coherence as well as collective phenomena as probed by heat capacity experiments. We discuss also the possibilities of application of molecule-based materials for magneto-cooling at low temperatures and the limitations in other temperature ranges. Perspectives for future developments are mentioned as well.
Descripción16 pages, 14 figures.-- El pdf del artículo es la versión post-print.
Versión del editorhttp://dx.doi.org/10.1039/b603738k
URIhttp://hdl.handle.net/10261/19527
DOI10.1039/b603738k
ISSN1473-7604
Aparece en las colecciones: (ICMA) Artículos
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