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Título:	Microsize and nanosize BPO4 from pyrolysis of a carborane-substituted polyphosphazene
Autor:	Díaz, Carlos; Jiménez, Josefina CSIC ORCID; Laguna, Antonio CSIC ORCID; Valenzuela, Maria Luisa
Palabras clave:	Polyphosphazenes Carborane Boron Nanoparticles Organometallic polymers Pyrolysis
Fecha de publicación:	28-oct-2006
Editor:	Springer Nature
Citación:	Journal of Inorganic and Organometallic Polymers and Materials 16(3): 211-218 (2006)
Resumen:	Pyrolysis in air of the carborane-substituted polyphosphazene, {[NP({OCH2}2C2B10H10)]0.5 [NP({OCH2}2C2B9H10· NBu4)]0.5} n affords BPO4 crystals of varied sizes in the micro and nano regime.The materials were characterised by IR spectroscopy, SEM-EDAX, TEM, X-ray diffraction, and DTA analysis. A possible mechanism for the formation of these materials is discussed and compared with that found for the formation of metallic nanostructured materials from the pyrolysis of anchored organometallic derivatives of polyphosphazenes.
Descripción:	8 pages, 4 figures, 6 scheme.-- et al.
Versión del editor:	http://dx.doi.org/10.1007/s10904-006-9047-6
URI:	http://hdl.handle.net/10261/19495
DOI:	10.1007/s10904-006-9047-6
ISSN:	1574-1443
Aparece en las colecciones:	(ICMA) Artículos

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Microsize and nanosize BPO4 from pyrolysis of a carborane-substituted polyphosphazene