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Roof-shaped pyrazaboles as a structural motif for bent-core liquid crystals

AuthorsCavero, Emma; Lydon, Donocadh P.; Uriel, Santiago; Fuente, M. Rosario de la; Serrano, José Luis; Giménez, Raquel
KeywordsBen-core molecules
Liquid crystals
Issue DateMay-2007
CitationAngewandte Chemie 119(27): 5267-5269 (2007)
AbstractBoron coordination compounds with a roof-shaped morphology (see structure) exhibit unusual liquid-crystalline behavior with a transition (represented by the red arrow) from a nematic mesophase with similar characteristics to those of some bent-core liquid crystals to a compact lamellar phase with a chiral organization (see microphotographs of the two phases).
Description3 pages, 4 figures, 1 scheme.-- Supporting information for this article is available: http://www.angewandte.org or from the author.-- See also: Angewandte Chemie International Edition 46(27): 5175-5177 (2007)
Publisher version (URL)http://dx.doi.org/10.1002/ange.200700820
Appears in Collections:(ICMA) Artículos
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