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http://hdl.handle.net/10261/19444
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Castarlenas, Ricardo | - |
dc.contributor.author | Esteruelas, Miguel A. | - |
dc.contributor.author | Oñate, Enrique | - |
dc.date.accessioned | 2009-12-10T08:38:41Z | - |
dc.date.available | 2009-12-10T08:38:41Z | - |
dc.date.issued | 2007-03-15 | - |
dc.identifier.citation | Organometallics 26(8): 2129–2132 (2007) | en_US |
dc.identifier.uri | http://hdl.handle.net/10261/19444 | - |
dc.description | 4 pages, 3 figures. | en_US |
dc.description.abstract | The complex [(η6-p-cymene)OsCl(CHPh)(IPr)]OTf (1) releases the arene in acetonitrile at 40 °C. The resulting 12-valence-electron metallic fragment is trapped by the solvent to afford the tris(solvento) compound [OsCl(CHPh)(NCCH3)3(IPr)]OTf (2), which reacts with AgOTf in acetonitrile at room temperature to give the tetrakis(solvento) derivative [Os(CHPh)(NCCH3)4(IPr)](OTf)2 (3). In dichloromethane at 40 °C, the treatment of 1 with triisopropylphosphine and triphenylphosphine yields the unsaturated five-coordinate mixed phosphine−NHC hydride−alkylidyne−osmium species [OsHCl(CPh)(IPr)(PR3)]OTf (R = iPr (4), Ph (5)). | en_US |
dc.description.sponsorship | Financial support from the MCYT of Spain (Project No. CTQ2005-00656) and the Diputación General de Aragón (E35) is acknowledged. R.C. thanks the CSIC and the European Social Fund for funding through the I3P Program. | en_US |
dc.format.extent | 10752 bytes | - |
dc.format.mimetype | application/octet-stream | - |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | closedAccess | en_US |
dc.title | Preparation and structure of alkylidene−osmium and hydride−alkylidyne−osmium complexes containing an n-heterocyclic carbene ligand | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1021/om070065b | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1021/om070065b | en_US |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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