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http://hdl.handle.net/10261/19409
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Byabartta, Prithwiraj | - |
dc.date.accessioned | 2009-12-09T10:46:45Z | - |
dc.date.available | 2009-12-09T10:46:45Z | - |
dc.date.issued | 2007-04 | - |
dc.identifier.citation | Transition Metal Chemistry 32(3): 314-324 (2007) | en_US |
dc.identifier.issn | 0340-4285 | - |
dc.identifier.uri | http://hdl.handle.net/10261/19409 | - |
dc.description | 11 pages, 5 figures, 2 schemes. | en_US |
dc.description.abstract | Silver assisted de-bromination gives [Au2(dppm/dppe/dppa) (OTf)2], which on reaction with 4,4′-bpy and gold(I) phosphines in CH2Cl2 medium, by the self assembly technique, leads to [(PPh3)Au(4,4′-bpy)Au(PPh3)], (1a–1d,2), [{Au2(dppm/dppe/dppa)}{(4,4-bpy)Au(PPh3)}2](NO3)4, (3), [{Au4(dppm/dppe/dppa)2(4,4-bpy)2}](OTf)4, (4), [{(PPh3)AuI(4,4′-bpy)}2AuIII(C6F5/Mes)](NO3)3, (5) [dppm/dppe/dppa =diphenyl phosphino-methane(a), –ethane(b), ammine(c), C6F5/Mes pentafluorophenyl/mesitylene]. The maximum molecular peak of the corresponding molecule is observed in the ESI mass spectrum. Ir spectra of the complexes show –C=C–, –C=N–, as well as phosphine, mesitylene and pentafluorophenyl stretching. The 1H-NMR spectra as well as 31P(1H)-NMR suggest solution stereochemistry, proton movement and phosphorus proton interaction. Considering all the moities there are a lot of carbon atoms in the molecule reflected by the 13C(H)-NMR spectrum. In the 1H–1H COSY spectrum of the present complexes and contour peaks in the 1H–13C-HMQC spectrum, assign the solution structure and stereoretentive transformation in each step. | en_US |
dc.description.sponsorship | The Ministerio de Education Y Ciencia (Grant no. SB2004-0060), Madrid is thanked for financial support. | en_US |
dc.format.extent | 259768 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Springer Nature | en_US |
dc.rights | closedAccess | en_US |
dc.title | Gold(I)-Gold(III)-4,4′-bpy-phosphine complexes: Synthesis and multinuclear NMR study | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1007/s11243-006-0167-1 | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1007/s11243-006-0167-1 | en_US |
dc.identifier.e-issn | 1572-901X | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (ICMA) Artículos |
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