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http://hdl.handle.net/10261/19404
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Carmona, Daniel | - |
dc.contributor.author | Medrano, Roberto | - |
dc.contributor.author | Dobrinovich, Isabel T. | - |
dc.contributor.author | Lahoz, Fernando J. | - |
dc.contributor.author | Ferrer, Joaquina | - |
dc.contributor.author | Oro, Luis A. | - |
dc.date.accessioned | 2009-12-09T09:53:01Z | - |
dc.date.available | 2009-12-09T09:53:01Z | - |
dc.date.issued | 2006-12-15 | - |
dc.identifier.citation | Journal of Organometallic Chemistry 691(26) 15 December 2006, Pages 5560-5566 | en_US |
dc.identifier.issn | 1381-1177 | - |
dc.identifier.uri | http://hdl.handle.net/10261/19404 | - |
dc.description | 6 pages, 3 tables, 2 figures, 1 schema | en_US |
dc.description.abstract | Half-sandwich complexes of formula [(ηn-ring)MClL]PF6 [L = (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline; (ηn-ring)M = (η5-C5Me5)Rh; (η5-C5Me5)Ir; (η6-p-MeC6H4iPr)Ru; (η6-p-MeC6H4iPr)Os] have been prepared and spectroscopically characterised. The molecular structures of the rhodium and iridium compounds have been determined by X-ray crystallography. The related solvate complexes [(η5-C5Me5)ML(Me2CO)]2+ (M = Rh, Ir) are active catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene. | en_US |
dc.description.sponsorship | We thank the Dirección General de Investigación Científica y Técnica for financial support (Grant BQU 2003/1096). | en_US |
dc.format.extent | 13824 bytes | - |
dc.format.mimetype | application/vnd.ms-excel | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.rights | closedAccess | en_US |
dc.subject | Phosphinoferrocenyloxazoline ligands | en_US |
dc.subject | Rhodium | en_US |
dc.subject | Iridium | en_US |
dc.subject | Ruthenium | en_US |
dc.subject | Osmium | en_US |
dc.subject | Asymmetric catalysis | en_US |
dc.subject | Molecular structures | en_US |
dc.title | Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(S<sub>p</sub>)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1016/j.jorganchem.2006.09.003 | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.jorganchem.2006.09.003 | en_US |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
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