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dc.contributor.authorCarmona, Daniel-
dc.contributor.authorMedrano, Roberto-
dc.contributor.authorDobrinovich, Isabel T.-
dc.contributor.authorLahoz, Fernando J.-
dc.contributor.authorFerrer, Joaquina-
dc.contributor.authorOro, Luis A.-
dc.date.accessioned2009-12-09T09:53:01Z-
dc.date.available2009-12-09T09:53:01Z-
dc.date.issued2006-12-15-
dc.identifier.citationJournal of Organometallic Chemistry 691(26) 15 December 2006, Pages 5560-5566en_US
dc.identifier.issn1381-1177-
dc.identifier.urihttp://hdl.handle.net/10261/19404-
dc.description6 pages, 3 tables, 2 figures, 1 schemaen_US
dc.description.abstractHalf-sandwich complexes of formula [(ηn-ring)MClL]PF6 [L = (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline; (ηn-ring)M = (η5-C5Me5)Rh; (η5-C5Me5)Ir; (η6-p-MeC6H4iPr)Ru; (η6-p-MeC6H4iPr)Os] have been prepared and spectroscopically characterised. The molecular structures of the rhodium and iridium compounds have been determined by X-ray crystallography. The related solvate complexes [(η5-C5Me5)ML(Me2CO)]2+ (M = Rh, Ir) are active catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene.en_US
dc.description.sponsorshipWe thank the Dirección General de Investigación Científica y Técnica for financial support (Grant BQU 2003/1096).en_US
dc.format.extent13824 bytes-
dc.format.mimetypeapplication/vnd.ms-excel-
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.rightsclosedAccessen_US
dc.subjectPhosphinoferrocenyloxazoline ligandsen_US
dc.subjectRhodiumen_US
dc.subjectIridiumen_US
dc.subjectRutheniumen_US
dc.subjectOsmiumen_US
dc.subjectAsymmetric catalysisen_US
dc.subjectMolecular structuresen_US
dc.titleSynthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(S<sub>p</sub>)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazolineen_US
dc.typeartículoen_US
dc.identifier.doi10.1016/j.jorganchem.2006.09.003-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.jorganchem.2006.09.003en_US
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextNo Fulltext-
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