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dc.contributor.authorFontàs, Claudia-
dc.contributor.authorMarguí, Eva-
dc.contributor.authorQueralt Mitjans, Ignacio-
dc.date.accessioned2009-12-07T12:54:45Z-
dc.date.available2009-12-07T12:54:45Z-
dc.date.issued2009-01-
dc.identifier.citationX-Ray Spectrom. 38: 9–17 (2008)en_US
dc.identifier.issn0049-8246-
dc.identifier.urihttp://hdl.handle.net/10261/19385-
dc.description.abstractThis work was aimed to achieve improved instrumental sensitivity and detection limits for the determination of several elements (Cr (VI), Cd, Pd and Pt) in liquid samples by using conventional energy dispersive x-ray fluorescence (EDXRF) and wavelength dispersive x-ray fluorescence (WDXRF) instrumentation. In all cases, the preconcentration of metals from liquid solutions was performed by using membranes activated with the commercial anionic exchanger Aliquat 336 (a quaternary ammonium salt), which also permits the isolation of Cr (VI) species for further x-ray fluorescence analysis. Likewise, for the improvement of the instrumental sensitivity, a special sample holder device was used in the case of Cd determination by EDXRF (tungsten x-ray source) instrumentation. ForWDXRF analysis, the spectral evaluation was carried out by the integration of the peak area (using WinQXAS software) instead of the common net peak line intensity traditionally used in conventional WDXRF systems.With the proposed methodologies, a linear response between themetal present in the aqueous solutions and the metal extracted in the membranes was obtained, highlighting the feasibility of using these membranes as standards for x-ray fluorescence spectrometry (XRF) analysis for future determination of these elements when contained in liquid samples. Concerning the calculated detection limits, in all cases, theywere in the μg l−1 range, indicating the possibilities of the proposed methodology for trace determination content of Cd, Cr(VI), Pd and Pt in liquid solutions using conventional EDXRF andWDXRF instrumentation.en_US
dc.description.sponsorshipThis study was financed by the Spanish National Research Programme (projects CGL2007-66861-C04 and Consolider Tragua, ref. CSD2006-00044).en_US
dc.format.extent271183 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherJohn Wiley & Sonsen_US
dc.rightsclosedAccessen_US
dc.titleImprovement approaches for the determination of Cr(VI), Cd(II), Pd(II) and Pt(IV) contained in aqueous samples by conventional XRF instrumentationen_US
dc.typeArtículoen_US
dc.identifier.doi10.1002/xrs.1093-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://www3.interscience.wiley.com/journal/120750829/abstract?CRETRY=1&SRETRY=0en_US
dc.identifier.e-issn1097-4539-
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