English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/19358
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Dendritic liquid-crystalline fullerene-ferrocene dyads

AuthorsCampidelli, Stéphane; Pérez, Laura; Rodríguez-López, Julián; Barberá, Joaquín; Langa, Fernando; Deschenaux, Robert
KeywordsFerrocene
Fullerene
Supramolecular organization
Issue Date27-Feb-2006
PublisherElsevier
CitationTetrahedron 62(9): 2115-2122 (2006)
AbstractFirst- and second-generation ferrocene-based dendrimers, fullerene and a second-generation liquid-crystalline poly(arylester) dendrimer carrying four cyanobiphenyl units were assembled to elaborate polyfunctional materials displaying mesomorphic and electronic properties. The targeted compounds gave rise to enantiotropic smectic A phases and organized into bilayer structures within the smectic layers. Cyclic voltammetry investigations revealed oxidation and reduction processes in agreement with the presence of both ferrocene and fullerene units. Finally, strong quenching of the fluorescence was obtained for the fullerene-ferrocene dyads suggesting efficient elecron transfer from the ferrocene-based dendrimer to fullerene.
Description8 pages, 4 figures, 2 tables.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2005.10.065
URIhttp://hdl.handle.net/10261/19358
DOI10.1016/j.tet.2005.10.065
ISSN0273-1177
Appears in Collections:(ICMA) Artículos
Files in This Item:
There are no files associated with this item.
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.