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Dactylomelatriol, a biogenetically intriguing omphalane-derived marine sesquiterpene

AuthorsDíaz-Marrero, Ana R. ; Rosa, José M. de la ; Brito, Inmaculada ; Darias, José ; Cueto, Mercedes
Marine sesquiterpene
Issue Date5-Jan-2012
PublisherACS Publications
CitationJournal of Natural Products 75(1): 115-118 (2012)
AbstractDactylomelatriol (1), obtained from the sea hare Aplysia dactylomela, is the first naturally occurring omphalane-derived sesquiterpene from the marine environment. From this species the known chamigrene and modified bisabolene sesquiterpenes 2-6 were also isolated. The structure and relative configuration of 1 were established by spectroscopic evidence. Its chemical structure is related to omphalic acid, the unique terrestrial-derived omphalane sesquiterpene isolated from a liverwort. A biogenetic route for this compound is proposed. The antimicrobial activities of compounds 1-6 were evaluated against a panel of microorganisms.
Publisher version (URL)https://pubs.acs.org/doi/10.1021/np200845f
Identifiersdoi: 10.1021/np200845f
issn: 0163-3864
e-issn: 1520-6025
Appears in Collections:(IPNA) Artículos
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