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Experimental and theoretical evidence of the first Au(I)Bi(III) interaction

AuthorsFernández, Eduardo J.; Laguna, Antonio ; López-de-Luzuriaga, José M.; Monge, Miguel; Nema, Mihai; Olmos, M. Elena; Pérez, Javier; Silvestru, Cristian
Issue Date2007
PublisherRoyal Society of Chemistry
CitationChemical Communications (6): 571-573 (2007)
AbstractComplex [Au(C6F5)2][Bi(C6H4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).
Description3 pages, 3 figures, 1 scheme.-- Published as an advance article on the web 15th Nov. 2006.
Publisher version (URL)http://dx.doi.org/10.1039/b613365g
Appears in Collections:(ICMA) Artículos
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