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| Title: | Gold-catalyzed benzylic CH activation at room temperature |
Authors: | Hashmi, A. Stephen K.; Schäfer, Sascha; Wölfle, Michael; Díez-Gil, César; Fischer, Peter; Laguna, Antonio CSIC ORCID; Blanco, M. Carmen CSIC ORCID; Gimeno, M. Concepción CSIC ORCID | Keywords: | Alkynes C---H activation Gold Heterocycles Homogeneous catalysis |
Issue Date: | Jul-2007 | Publisher: | Wiley-Blackwell | Citation: | Angewandte Chemie International Edition in English 46(32): 6184-6187 (2007) | Abstract: | A tale of the unexpected: Coordinating and potentially chelating groups allow gold-catalyzed benzylic CH activation at room temperature. Substrates with additional nucleophilic substituents undergo unexpected dimerizations, in which eight new bonds are formed (see scheme). | Description: | 4 pages, 7 schemes, 1 figure, 2 tables.-- Supporting information for this article is available: http://www.angewandte.org or from the author. | Publisher version (URL): | http://dx.doi.org/10.1002/anie.200701521 | URI: | http://hdl.handle.net/10261/19302 | DOI: | 10.1002/anie.200701521 | ISSN: | 1433-7851 |
| Appears in Collections: | (ICMA) Artículos |
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