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Title

Gold(I) and palladium(II) thiolato complexes containing water-soluble phosphane ligands

AuthorsVergara, Elena; Miranda, Susana; Mohr, Fabian; Cerrada, Elena ; Tiekink, Edward R. T.; Romero, Pilar ; Mendía, Aránzazu; Laguna, Mariano
KeywordsPhosphane ligands
Palladium
Thiolato complexes
Gold
Issue DateMay-2007
PublisherWiley-Blackwell
CitationEuropean Journal of Inorganic Chemistry (18): 2926-2933 (2007)
AbstractWater-soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques including 2D NMR experiments, and the complexes [Au(S2CNEt2)(PTA)], trans-[Pd(SC5H4N)2(PTA)2] and trans-[Pd(SC5H4N)2(DAPTA)2] were additionally characterised by X-ray crystallography; the latter complex is one of the few structurally characterised DAPTA complexes.
Description8 pages, 1 table, 4 figures, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1002/ejic.200700112
URIhttp://hdl.handle.net/10261/19295
DOI10.1002/ejic.200700112
ISSN1434-1948
Appears in Collections:(ICMA) Artículos
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