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Synthesis, Characterization and X-ray Crystal Structures of New Ethylxanthato Complexes of Zinc(II) with N-donor Ligands

AuthorsAra, Irene ; El Bahij, Fatima; Lachkar, Mohamed
KeywordsZn(II) complexes
Xanthate ligands
N-donor ligands
Crystal structures
Issue DateJun-2006
CitationSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 36(5): 399-406 (2006)
AbstractZn(II) complexes of general formula [Zn(S2COEt)2L] [L=pyrazole (Hpz) 1; 3,5-dimethylpyrazole (Hdmpz) 2; 2-pyridylamine (pyam) 3; phenyl 2-pyridylamine (phpyam) 4; 2,2'-dipyridylamine (dpyam) 5; 1,4-pyrazine (pyr) 6] have been synthesized and characterized by elemental analyses and IR and NMR spectroscopy. The crystal structures of complexes 2, 5 and 6 have been determined by X-ray diffraction, showing different geometries and modes of coordination of the xanthate ligand depending on the type of N-donor ligand.
Publisher version (URL)http://dx.doi.org/10.1080/15533170600732569
Appears in Collections:(ICMA) Artículos
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