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Gold(I)-diphenylphosphinomethane–arylazoimidazole: synthesis and multinuclear NMR investigation.
|Authors:||Byabartta, Prithwiraj; Laguna, Mariano|
|Citation:||Transition Metal Chemistry 32(2): 180-186 (2007)|
|Abstract:||Reaction of [Au2(dppm)Cl2] with AgOTf in CH2Cl2 medium followed ligand addition and leads to [Au2(dppm)(RaaiR′)](OTf) [RaaiR′ = p-R–C6H4–N = N–C3H2–NN–1–R′, (1–3), abbreviated as N,N′-chelator, where N(imidazole) and N(azo) represent N and N′, respectively; R = H (a), Me (b), Cl (c) and R′ = Me (1), CH2CH3 (2), CH2Ph (3), OSO2CF3 is the triflate anion, and dppm is the diphenylphosphinomethane-ring]. The 1H-n.m.r. spectral measurements suggest methylene, –CH2–, in RaaiEt gives a complex AB type multiplet while in RaaiCH2Ph it shows AB type quartets with coupling constant of avg. 6 Hz. Considering all the moities there are a lot of different carbon atoms in the molecule which gives a lot of different peaks in the 13C-n.m.r spectrum. In the 1H–1H-COSY spectrum of the present complexes and contour peaks in the 1H–13C-HMQC spectrum in the present complexes, assign the solution structure and stereoretentive transformation in each step.|
|Description:||7 pages, 2 figures.|
|Publisher version (URL):||http://dx.doi.org/10.1007/s11243-006-0145-7|
|Appears in Collections:||(ICMA) Artículos|
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