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Título: | Supramolecular chirality of columnar mesophases consisting of H-bonded complexes of melamine and polycatenar benzoic acids |
Autor: | Barberá, Joaquín CSIC ORCID; Romero, Pilar CSIC ORCID ; Serrano, José Luis CSIC ORCID; Sierra, Teresa CSIC ORCID | Palabras clave: | Organic compounds Aromatics Synthon Mesophases |
Fecha de publicación: | 2006 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry 2006(16): 3768-3773 (2006) | Resumen: | The present work describes a series of H-bonded complexes consisting of a melamine derivative and polycatenar acids that show columnar liquid crystalline behaviour. Chirality has been transferred from the molecular blocks (either the acids, A3* and A4*, or the melamine, T2*) to the columnar organization. Particular effort and attention has been paid to structural characterization by NMR techniques [1D NMR spectroscopy and diffusion-ordered spectroscopy (DOSY) experiments] of the complexes in solution. The mesomorphic arrangements of all the complexes have been studied by polarizing optical microscopy (POM), differential scanning microscopy (DSC) and powder X-ray diffraction. The chiral nature of the supramolecular organization in the mesophase has been confirmed by circular dichroism spectroscopy on neat samples over a range of temperatures. | Descripción: | 6 pages, 6 figures, 2 tables, 2 schemes.-- et al. | Versión del editor: | http://dx.doi.org/10.1039/b608066a | URI: | http://hdl.handle.net/10261/19109 | DOI: | 10.1039/b608066a | ISSN: | 0959-9428 |
Aparece en las colecciones: | (ICMA) Artículos |
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