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Title

A square-planar organoiron(III) compound with a spin-admixed state

AuthorsAlonso, Pablo J. CSIC ORCID; Arauzo, Ana B. CSIC ORCID; Forniés, Juan CSIC; García-Monforte, M. Ángeles CSIC; Martín, Antonio CSIC ORCID; Martínez, Jesús I. CSIC ORCID; Menjón, Babil CSIC ORCID; Rillo, Conrado CSIC ORCID CVN ; Sáiz-Garitaonandia, José J.
KeywordsEPR spectroscopy
Homoleptic compounds
Iron
Magnetic properties
Moessbauer spectroscopy
Issue Date15-Sep-2006
PublisherWiley-Blackwell
CitationAngewandte Chemie International Edition 45(40): 6707-6711 (2006)
AbstractSquare-planar iron(III) species bearing no axial ligands can still behave as spin-admixed systems (S=3/2, 5/2). The highly unusual homoleptic -organoiron complex [Li(thf)4][FeIII(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system.
Description5 pages, 3 figures, 1 table, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1002/anie.200601774
URIhttp://hdl.handle.net/10261/19076
DOI10.1002/anie.200601774
ISSN1433-7851
Appears in Collections:(ICMA) Artículos

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